An estimated 10,000 Napoli supporters, including the team's most famous player Diego Maradona, are expected to make the trip to the Spanish capital for the first competitive meeting with Real Madrid since the 1987.
Former Inter Milan, Liverpool and Chelsea manager Rafael Benitez will return to Italy to take charge of Serie A club Napoli.
Liverpool received a relatively kind draw for the group stage of this year's Champions League
Roundup of the matches being held across major football leagues in Europe on Sunday
Napoli striker Gonzalo Higuain scored twice to put them top of Serie A with an extraordinary 2-1 win over Inter Milan who twice hit the woodwork in stoppage time after playing the entire second half with 10 men on Monday.
Napoli booked a clash with AS Roma in the Italian Cup semi-finals after a late instinctive Gonzalo Higuain backheel lifted Rafael Benitez's side to a 1-0 win over Lazio on Wednesday.
Senad Lulic scored a late goal to give Lazio a 1-0 win at Napoli which sent them into the Coppa Italia final and added to Rafael Benitez's problems on Wednesday.
Atletico Madrid secured a hard-fought 2-1 home victory over Real Betis in La Liga on Sunday thanks to an own-goal by Rui Silva and a header by Alvaro Morata as Diego Simeone's side ended a three-game winless run in all competitions.
Juventus have completed the signing of Argentina forward Gonzalo Higuain from Napoli.
Liverpool failed to muster a single shot on target in a Champions League game for the first time since a 1-0 defeat to Benfica in February 2006.
Jose Callejon took advantage of Napoli's numerical advantage in the 48th minute of the playoff round second leg tie, handing them an away goal which, added to their 2-0 win from the first leg, effectively ended Nice's challenge as it left the French side needing to score four goals.
Napoli rediscovered their scoring touch as they brushed aside Inter Milan 3-0 on Friday, sending their opponents' new coach Stefano Pioli back to the drawing-board.
Images from the UEFA Champions League group matches played on Tuesday night.
Gonzalo Higuain scored his 30th league goal of the season but was later sent off and had to be restrained by his team mates as Napoli lost 3-1 at Udinese on Sunday, severely denting their Serie A title hopes.
The Polish player was driving through the Varcaturo district of Naples at around 2 am when the motorbike blocked the road and forced him to stop, the report said.
Argentina have called up Mallorca's Spanish defender Pablo Maffeo for the first time ahead of this month's World Cup qualifiers against Uruguay and Brazil in the squad announced by its FA on Friday.
Gonzalo Higuain has led Napoli's challenge for their first Serie A title since 1990 with a remarkable 26 goals in 28 league games, yet the fiery Argentine does not seem to have enjoyed a single moment of it. Higuain, an out-and-out striker who can safely be described as an old-fashioned number nine, stomps around the field with an expression that suggests he is carrying the whole world on his shoulders. There is always something for the 28-year-old to gesticulate angrily about, whether it be a refereeing decision, a team mate failing to pass him the ball or his coach deciding to substitute him. In his last outings, he kicked a water bottle over in disgust after being substituted at Fiorentina and then failed to join his team mates in saluting the crowd following Saturday's 3-1 win over Chievo, despite scoring in both games. His goal celebrations invariably involve thumping his chest and seem to be more an act of defiance than a show of joy.
Chelsea named former Napoli boss Maurizio Sarri as the new head coach on a three-year term on Saturday, a day after parting ways with another Italian manager Antonio Conte.
Two goals in three devastating second-half minutes helped Napoli reach the Italian Cup final on Wednesday with a 3-0 win over AS Roma in the second leg of their semi-final in Naples, to clinch the tie 5-3 on aggregate.
Ibrahimovic was forced off with a muscle problem with 11 minutes remaining, and the Swede was pictured sitting on the bench with an ice pack strapped to the back of his left leg.
Carlo Ancelotti's side held a two-goal lead at halftime thanks to strikes from Dries Mertens and Kostas Manolas, but Balotelli pulled one back as Brescia rallied after the break.
Inter Milan captain Lautaro Martinez struck a last-gasp goal to snatch a dramatic 1-0 win over 10-man Napoli as they claimed their third successive Italian Super Cup title on Monday.
Napoli jumped to second place in Serie A thanks to a laboured 1-0 win at lowly Cagliari while fellow title hopefuls Inter Milan suffered a 1-0 defeat at Parma in Monday's late game.
Stand-in defender Vlad Chiriches atoned for an early blunder by scoring his first Serie A goal to help Napoli come from behind and beat Chievo 3-1 in Serie A on Saturday, putting them level at the top with Juventus.
Atalanta forward German Denis took advantage of shocking defending by Napoli to score twice in a 3-0 win over Rafael Benitez's exasperatingly inconsistent team on Sunday.
'I understood that if I dedicated myself solely to coaching, I could get much better at it'
Napoli have agreed to buy Spain centre back Raul Albiol from Real Madrid, the Serie A club said on Sunday.
Real Madrid produced a gutsy performance to earn a 1-0 win at Sevilla, on Sunday, which took them level on points at the top of La Liga
Napoli went down 3-1 at home to RB Leipzig, Arsenal and AC Milan enjoyed comfortable away wins, and Borussia Dortmund's Michy Batshuayi scored twice to secure a 3-2 victory in Europa League last 32, first leg action
Germany expects 2.7 million people to attend matches in stadiums across the country and some 12 million in its fan zones for outdoor viewing, including on a long stretch of turf laid out in front of Berlin's Brandenburg Gate.
Frustrated AC Milan missed the chance to seize top spot in Serie A when they were held to a 1-1 draw by Napoli at the San Siro on Sunday.
Napoli won their first major title since the Diego Maradona era, denied Serie A champions Juventus the double and handed their captain Alessandro Del Piero an unhappy end to 19 seasons at the club by beating the Turin side 2-0 in the Italian Cup final on Sunday.
Inter Milan staged a late smash-and-grab raid as goals by Mauro Icardi and Matias Vecino secured a 2-1 home win over Tottenham Hotspur in their Champions League Group B opener on Tuesday.
Striker Edinson Cavani scored a superb hat-trick to give Napoli a 3-1 home win over defending Serie A champions AC Milan on Sunday.
Napoli squandered a two-goal halftime lead, then scored two late goals to beat nine-man AC Milan 4-2 in a stormy Serie A match which saw eight other players booked on Saturday.
Napoli suffered an agonising exit from the Champions League after beating Premier League leaders Arsenal 2-0 on Wednesday.
Images from the Euro 2024 Group F matches between Georgia and Portugal; Czechia and Turkey in Germany on Wednesday.
Napoli forward Gonzalo Higuain is feeling the wrath of the club's fans following widespread reports he is about to jump ship and join bitter rivals Juventus. Italian media have reported that Juventus, Italian champions for the past five seasons, are on the point of signing the prolific Argentina striker, who last season scored a record 36 Serie A goals.
Arsenal manager Arsene Wenger has told his players to watch out for Napoli's quickfire counter-attacks when the two high-flying sides meet at the Emirates Stadium in Champions League Group F on Tuesday.
Marcos Alonso scored for Fiorentina and then almost immediately gifted Gonzalo Higuain the equaliser for Napoli in a pulsating, end-to-end 1-1 Serie A draw on Monday.